Document Type

Article

Publication Date

10-8-2014

Publication Title

Fuel Cells

Abstract

In this work, the fluid dynamics within a membrane-less microchannel fuel cell is analyzed computationally. The membrane-less design is a result of the laminar nature of the fluid flow at small Reynolds numbers, restricting the fuel and oxidant to the vicinity of the corresponding electrodes, without the need of a proton exchange membrane (PEM). However, the performance of such cells is limited by the slow diffusive mass transport near the electrodes, with a large fraction of the reactants leaving the channel without coming in contact with the catalytic surfaces, and thus not being used. We mitigate this problem through the introduction of channel surface modification consisting of angled grooves designed to create convective flows that direct the reactants toward the active surfaces. The grooved structures are optimized for maximum fuel utilization. Operation of this type of cells at Péclet numbers close to 2,500 leads to a performance doubling compared with unmodified cells. Moreover, this increase in efficiency is accompanied by a more uniform distribution of the current across the electrodes, reducing the possibility of hot spots being developed.

DOI

10.1002/fuce.201400047

Version

Postprint

Volume

14

Issue

6

Included in

Physics Commons

Share

COinS