Document Type

Article

Publication Date

1-1-2014

Publication Title

Journal of Power Sources

Abstract

The electrodes used for Proton Exchange Membrane Fuel Cells (PEMFCs) are typically painted or sprayed onto the membrane during manufacturing, making it difficult to directly characterize their mechanical behavior as a stand-alone material. An experimental-numerical hybrid technique is devised to extract the electrode properties from the experimentally measured properties of Nafion® 211 membrane1 and a membrane electrode assembly (MEA) based on Nafion® 211 membrane at various temperatures, humidities, and strain rates. Within the linear regime, the rule-of-mixtures assuming an iso-strain condition is used to calculate the rate-dependent Young's modulus of the electrodes. Beyond the linear regime, reverse analysis is conducted using finite element models of the MEA to determine the non-linear behavior of the electrodes. The mechanical damage mechanisms that occur in the MEA during tensile loading are also investigated through interrupted tension tests and then incorporated into the finite element models for determining the electrode behavior. The results suggest that the electrodes have similar behavior to Nafion® 211 membrane as functions of strain rate, temperature and humidity, but with lower Young's modulus and proportional limit.

Comments

This research has been supported by W.L. Gore & Associates under a grant (DE-FC36-086018052) from the United States Department of Energy.

DOI

10.1016/j.jpowsour.2013.07.013

Version

Postprint

Volume

245

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