A 2:1 complex of 1,3-bis­(9H-carbazol-9-yl)propane and tetra­chloro-p-benzoquinone (p-chloranil)

Authors

Mustafa Arslan, Sakarya University, Adapazari, Turkey
Randolph B. Krafcik
John Masnovi, Cleveland State UniversityFollow
Ronald J. Baker

Document Type

Article

Publication Date

9-15-2006

Publication Title

Acta Crystallographica Section E

Abstract

In the title electron donor–acceptor complex, C₂₇H₂₂N₂·0.5C₆Cl₄O₂, the p-chloranil mol­ecule lies on a crystallographic inversion center, which is located at the center of the benzene ring. In the crystal structure, one p-chloranil mol­ecule lies above and below the central rings of each donor group of two neighboring 1,3-bis­(9H-carbazol-9-yl)propane mol­ecules, with a ring-centroid separation of 3.444 (1) Å. The angle between the planes of the stacking rings of the carbazole and p-chloranil mol­ecules is 3.4 (2)°.

Recommended Citation

Arslan, M., Asker, E., Krafcik, R. B., Masnovi, J., & Baker, R. J. (2006). A 2:1 complex of 1,3-bis­(9H-carbazol-9-yl)propane and tetra­chloro-p-benzoquinone (p-chloranil). Acta Crystallographica Section E, 62(9), o4055-o4057. doi:10.1107/S1600536806031886

DOI

10.1107/S1600536806031886

Version

Publisher's PDF

Volume

62

Issue

9