Coordination Chemistry of Organic Nitric Oxide Derivatives
Document Type
Article
Publication Date
10-1-2019
Publication Title
Coordination Chemistry Reviews
Abstract
Organic derivatives of nitric oxide can serve as ligands for transition metals in a variety of fashions. This review surveys recent developments in the coordination chemistry of four main classes of organic NO derivatives: nitrosoalkanes and nitrosoarenes, azodioxides, and nitrosamines. Highlighted work includes evidence that nitrosoarenes can behave as redox-active (“non-innocent”) ligands, an expansion in the number of crystallographically characterized azodioxide complexes, and the synthesis of N-bound primary nitrosamines. Relevance to the bioinorganic chemistry of metalloenzymes is noted.
Recommended Citation
Emhoff, Kylin A.; Balaraman, Lakshmi; Salem, Ahmed M.H.; Mudarmah, Khalil I.; and Boyd, W. Christopher, "Coordination Chemistry of Organic Nitric Oxide Derivatives" (2019). Chemistry Faculty Publications. 500.
https://engagedscholarship.csuohio.edu/scichem_facpub/500
DOI
10.1016/J.CCR.2019.06.011
Volume
396
