Electrophilicity-Nucleophilicity Scale Also in the Gas Phase

Authors

Chagit Denekamp, Technion - Israel Institute of TechnologyFollow
Yana Sandlers, Technion - Israel Institute of TechnologyFollow

Document Type

Article

Publication Date

3-20-2006

Publication Title

Angewandte Chemie - International Edition

Abstract

Changing the state: The electrophilicity of benzhydryl cations (see formula) towards neutral amine nucleophiles in the gas phase was determined. It was found that the kinetics of electrophile-nucleophile gas-phase reactions correlate well with values known in solution although the actual electrophilicity parameters are considerably smaller in the gas phase. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Recommended Citation

Denekamp, Chagit and Sandlers, Yana, "Electrophilicity-Nucleophilicity Scale Also in the Gas Phase" (2006). Chemistry Faculty Publications. 542.
https://engagedscholarship.csuohio.edu/scichem_facpub/542

DOI

10.1002/anie.200503235

Volume

45

Issue

13